In the Aufbau principle, what does adding electrons to a smaller atom give it?

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In the context of the Aufbau principle, adding electrons to a smaller atom allows it to achieve a configuration that resembles that of larger atoms. This is because as electrons are added, they fill the available atomic orbitals according to the energy levels dictated by the principle. When these orbitals are filled, the distribution of electrons leads to a similar electron configuration pattern exhibited by larger atoms, especially those in the same group of the periodic table.

For example, as you progress down a group, elements gain electrons and shift to higher energy levels, but the valence electrons often maintain a consistent configuration. Therefore, when a smaller atom accumulates more electrons through the addition process, it mirrors the electron configuration of larger nearby atoms, thus sharing chemical properties and reactivity with those larger atoms. This connection highlights the periodic trends observed within the structure of the periodic table.

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